![]() (You can find more information about the rating methodologies used by the watchdogs on their websites.) “Charities that are A-rated generally spend at least 75 percent or more on their programs, so more of your money goes to causes you want to support,” says Stephanie Kalivas, analyst at CharityWatch.įor example, CharityWatch gave the Disabled Veterans National Foundation, which spent only 4 percent on its programs, an F, while the National Military Family Association, which spent 82 percent, received an A.Ĭharity Navigator focuses on financial metrics, accountability, and transparency. To become accredited by the BBB Wise Giving Alliance, charities must meet 20 standards, including adequate board oversight and strong conflict-of-interest policies, as well as the requirement that they spend at least 65 percent of their total expenses on their charitable programs and no more than 35 percent of their total contributions on fundraising.ĬharityWatch uses a letter-grade rating system that also looks at the percentage of overhead spent on programs, the cost of fundraising, and other measures of efficiency. Charities differ a lot in how much of the money they raise goes for programs instead of covering the expense of raising money. The best course of action before giving is to check out the charity with one or more of the major charity watchdogs, including the BBB Wise Giving Alliance, Charity Navigator, and CharityWatch.īy doing this vetting, you can feel more confident that the group you’re donating to deserves your support. According to a recent report by the Blackbaud Institute for Philanthropic Impact, 17 percent of contributions were made during December last year. Vetting charities is especially important now because December is typically the largest month for giving. Some organizations may spend too much on administrative and fundraising costs or are outright scammers. “You don’t want to choose a charity by the name alone, since your donation may go to a questionable group,” says Bennett Weiner, chief operating officer of the charity watchdog BBB Wise Giving Alliance. But you need to look carefully at the organization to make sure you are sending your money to the right place. If you’re looking for tips on choosing a charity, you can vet the charities you’re considering by checking the websites of the watchdog organizations mentioned here.ĭuring the holidays, many consumers receive a multitude of donation requests from charitable organizations, as well as crowdfunding sites and other online giving platforms.Ī charity’s name may signal worthy a cause, such as feeding the hungry or supporting veterans. Editor’s Note: Consumer Reports has not updated the specific charities mentioned in this story since November 2019.
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The berries are expertly sprinkled in so that there aren’t enough to overwhelm the consumer, but just enough to make their presence known. The original “Cap’n Crunch” may not have blown anyone away, but this certainly does. It takes the original “Cap’n Crunch” and adds candy-like berries to the mix. ![]() On top of that, it still has the savory taste of the original “Cap’n Crunch.” The saltiness combined with the savoriness makes for an excellent cereal. Unlike other peanut butter cereals, such as “ Reese’s Puffs ,” that are just overly sweet, “Cap’n Crunch: Peanut Butter Crunch” goes for a saltier approach. Next up is “Cap’n Crunch: Peanut Butter Crunch.” This is definitely one of the best peanut butter cereals on the market. It’s just a pleasant cereal that feels great to munch on. The cereal doesn’t do anything incredible but it also isn’t trying to. It has a nice, savory flavor to it with a hint of syrup-like sweetness. It won’t blow anyone’s mind, but it’ll keep the consumer coming back for more. The original “Cap’n Crunch” is a solid cereal. These include the original “Cap’n Crunch,” “Cap’n Crunch: Peanut Butter Crunch,” “Cap’n Crunch Berries” and “Cap’n Crunch: Oops! All Berries.” While there are some other limited edition flavors like “Cotton Candy Crunch” and “Chocolate Caramel Crunch,” the first four mentioned are what you’ll almost always see on store shelves. There are four main flavors of “Cap’n Crunch” created by Quaker Oats Company. ” However, if one were to want a box from the store, it might not be as simple as just grabbing the one that says “Cap’n Crunch.” In fact, there are several flavors of the cereal, some being good and tasty, while others are substandard. One of the most iconic cereals on the market is “ Cap’n Crunch. Scrolling will change the scale of the y-axis. Double clicking on the spectrum will revert it to the full view. You can easily change the view of the spectrum by clicking and dragging to zoom in on the x-axis. But with all widgets, you can resize or maximize them to improve their use. The widget is initially small to conserve space. The 1H and 13C NMR spectra are instantly generated and displayed. To use the widget, just draw a structure on the main Doodle Board and then drag it onto the widget or its button. ![]() The simulations are based on empirical algorithms, with a database of incremental constants compiled from publications and some unpublished work ( ChemDoodle 3 contains a full reference list). The following images describe the NMR simulation widget to be included in ChemDoodle 3. Switching up the fonts and matching peaks with chemical structures has never been easier or more elegant. Of course, all colors and fonts are editable as well. The remaining images show off the new NMR simulation widget. The first three images are of spectra loaded into ChemDoodle from JCAMP files and customized. The following are a few preview images generated from the development copy of ChemDoodle 3. Many more functions will be implemented in the next year for complete spectral manipulation, rivaling other spectroscopic editors. The features are pretty standard for ChemDoodle 3, allowing you to change the view, colors and axes. The interface is intuitive and the output is interactive. All variables can be customized, including radio frequency, temperature, and solvent. Additionally, of the new widgets added, one is a NMR simulator for quick assessment of 1H and 13C spectra. The JCAMP specification has been implemented so Mass Spectrometry, Infrared Spectroscopy and Nuclear Magnetic Resonance Spectroscopy output can be loaded and manipulated. One major new capability of ChemDoodle 3 is the inclusion of spectroscopic content. 2006, 78, 1897-1970.We certainly have been busy with ChemDoodle 3 development as its release approaches. Graphical Representation of Stereochemical configuration. Algorithmic Analysis ofĬahn−Ingold−Prelog Rules of Stereochemistry: Proposals for Revised Rules and a Guide for Machine CHEMINFORMATICS FOR GENOME-SCALE METABOLIC RECONSTRUCTIONS. The CIP System Again: Respecting Hierarchies Is Always a Must. Comparison of Constitutional Properties in the CIP System: The CIP Sequence Rule 1. Implementation of the Cahn-Ingold-Prelog System for Stereochemical Perception in the The CIP Sequence Rules: Analysis and Proposal for a Revision. Basic Principles of the CIP-System and Proposals for a Revision. Specifcation of Configuration about Quadricovalent Asymmetric Atoms. These stereochemical features are resolved in Then click on the molecule to see the answer. See if you can determine how many stereochemical features are present and what their configurationsĪre ( hint: just because an atom has a wedge bond attached does not mean it is a stereochemical feature). A sample of the variety and scope of the Hanson validation suite is provided here for your verification. and is 100% accurate in all 300 test cases provided. ![]() The CIP algorithm in ChemDoodle is validated against the test suite provided by Hanson et. to remove any ambiguities and describe a completely consistent system for CIP assignments.ĬhemDoodle 2D implements all 6 current CIP rules as well as auxilliary desciptors and mancude ring support. The most recent CIP rules from IUPAC were then algorithmically analyzed and standarized by Hanson et al. These rules were adopted by IUPAC for naming standards and fully described in the Blue books. While flawed, they have seen many revisions over the decades and were clarified by the work of Paulina Mata. The CIP rules have long been the standard for describing configurations of stereochemical features in a molecule. The ChemDoodle stereochemistry system is incredibly thorough andĬan even resolve drawn projections, examples below. Stereochemical feature in the sketcher below and press the Stereochemical configurations in 2D and 3D. References may beĬhemDoodle has an expert system to recognize and resolve Over the decades and more recently with the work of Paulina Mata and from Hanson et. Greatly simplified so students can more easily understand it, as the CIP algorithm is incredibly complex, To make things even more difficult, CIP rules have long been the standardįor assinging parity to stereochemical features, but such instruction is often Topic, especially when it comes to the representation of stereochemical information in 2D and 3D. Stereochemistry is not an easy concept to communicate, and much of chemistry education involves trying to master the Stereochemistry is an important concept in chemisty and is essential for understanding chemical structure. ![]() AC Reset Button Not Working? Call One Hour Since most window air conditioners do not have a reset button, you’ll need to unplug it for a few minutes to dissipate the charge.Īfter plugging it back in and turning the circuit back on, the window AC unit should reset and be operational again. Place your hand by the vents to confirm that cold air is blowing through your ductwork. After a few seconds, your air conditioner should start up. You’ve successfully completed a reset! Next, go to your thermostat and make sure it’s set to “cool” and a temperature that’s lower than the current temperature inside your home. Flip all switches, including the one in your breaker panel to the on position. Hold down the reset button for 3 to 5 seconds and then release.(If you can’t find it, most are published online for quick reference). If you’re having a tough time finding it, consult your owner’s manual. These buttons tend to be red and quite small. Most air conditioning units are equipped with a reset button. Also, flip the power switch your AC unit is connected to outside to the off position. Start at your circuit breaker panel and flip the breaker that powers your AC. ![]() If you are familiar with your AC unit, and comfortable moving forward, follow the simple instructions below. Please check your warranty guidelines before attempting to reset your air conditioner. As a final precautionary note, accessing your resent button may require you to open your condensing unit plan and with certain units, this could impact your warranty. While resetting an air conditioner is an easy task, if you are uncertain or uncomfortable, please contact an HVAC professional to assist by requesting an appointment with One Hour Heating & Air Conditioning. Sometimes a hard reset of your AC can solve that problem. This typically happens after a power outage and is in place to prevent fires and explosions.Ī reset can also correct an AC that’s only blowing warm air, even when the thermostat is set to “cool.” There are a handful of reasons your AC could be blowing warm air, but one of them is a general thermostat error. The most common reason for an AC unit requiring a reset is when the protection circuit breaker in your AC unit kicks in. Why Do I Need to Reset My Air Conditioner? Even older models that suddenly stop working can benefit from a reset, especially after a power outage. Like many appliances around your house, air conditioners are getting smarter and sometimes require a good old-fashioned reset. If you’ve ever asked an IT professional why your computer isn’t working, they may have responded with a question: “Have you tried restarting it?” ![]() ![]() ]: massive target, do not use as commander. Power dependant on other slivers being present. I also have all 5(6) sliver commanders, and here is my assessment of them: The way I keep my deck at a reasonable power level for my playgroup (mostly casual with a few very strong decks that quickly become archenemies) is by using Temples and tri lands instead of shocks and fetches etc. Slivers are my favourite tribe, and I have had a sliver deck for years. ![]() But, the best Sliver commander in my opinion with The First Sliver, even when built as tribal deck.Ī Sliver deck with the right manabase and support is terrifying to anyone who doesn't know how to keep them in check. They seem to be able to move a little faster than just Hivelord since all he does is create indestructible Slivers (strong, but can be dealt with easily). If you're still adamant on building Sliver-Tribal, I would suggest going with Overlord or Queen (if you have the budget for her). I'd like to note that my duel lands are all proxies I bought on Etsy, I did not spend 3k on that deck haha (I did however spend the other about 1k on the other 90 cards). This is my First Sliver deck if you're curious. I ended up switching to The First Sliver/Food Chain combo deck, which when built to play anywhere near a competitive power level, doesn't really have Slivers in it. My problem with Slivers is that they are incredibly easy to deal with being creatures, and thus the staying power of a Hivelord deck just isn't there, at least that's how it felt with my playgroup. Personally, I like being the threat on the table (hence having a Kaalia, Eldrazi, and Sliver deck). It was okay, but with just creatures and having the name "Sliver" you seem to get hated a little more. ![]() The organization suggests several safety measures, including using an experienced canyoneer as a beginner, knowing the landscape and conditions before setting out, wearing a helmet, and learning technical skills, such as repelling, well before trying canyoneering. Clear Creek, Pine Creek and Virgin River all lie downstream from the canyon, where the preliminary search was conducted.Ĭanyoneers typically rappel, rock climb, swim and hike their way through various types of canyon formations, and Zion is a well-known destination for the activity, according to Utah-based Canyoneering USA. The canyon takes one to two hours to traverse and features several technical elements, including swimming and a 30-foot rappel. Keyhole Canyon is a small slot canyon popular with canyoneers. Tuesday, saying on Twitter that "waterways (are) expected to reach dangerous levels." The park received close to 2 inches of rain between Sunday and Tuesday afternoons. The National Weather Service issued another flash flood warning for Zion National Park through 7:45 p.m. "We recommend that people pay attention to the weather before they decide to plan a trip or (to) make changes as they notice the weather is building," Baltrus said. She cautioned those who go hiking or canyoneering in southern Utah to be attentive to weather forecasts and adjust accordingly. This includes strong thunderstorms and intense rainfall that can take place over several hours or even just a few minutes. Today's tragedy also serves as a reminder to residents and those visiting our state to take appropriate precautions and be aware of the factors that contribute to dangerous flash floods. A full search in that area will resume Wednesday morning, Baltrus said, and a more extensive search of the canyon is planned for as soon as the weather and canyon terrain improves. It floods and it floods really fast."Ī cautious search downstream led to a fourth body being found, but those efforts were later also called off. "Really, we are not used to this kind of rain. "Any place that can flood might flood again tonight," Baltrus said. The search in the canyon was called off early Tuesday evening because of continued rain and the risk of further flooding in the area, she said. "As the search continues for the missing hikers, high water levels and continued rain showers pose further flash flooding concerns and have hampered searchers' access to the technical portions of the canyoneering route," Baltrus said in a statement. However, crews couldn't access the canyon because conditions remained too dangerous there. The group's vacant vehicles were spotted Monday evening, and search and rescue crews began looking for the hikers Tuesday morning after discovering they still had not left the canyon. The names of the people confirmed killed were not immediately released, pending notification of family members. The canyoneers who went missing were from California and Nevada and consisted of four men and three women in their 40s and 50s, according to Baltrus. "They told us the group was moving pretty slow," she said, noting those who notified the park made it out of the canyon safely. Nearly two-thirds of an inch of rain fell inside the national park within an hour.īaltrus said park officials received word from some other canyoneers "shortly before the flooding began" that there was another group still in the canyon. Three others remained unaccounted for Tuesday evening.Īll seven of the missing or deceased hikers were part of the same group that began canyoneering in the area a short time before flooding started around 4:30 p.m. The four victims were discovered downstream from Keyhole Canyon on Tuesday, park spokeswoman Aly Baltrus confirmed. ZION NATIONAL PARK - Three men and one woman have been killed in flash flooding in Zion National Park and three others are missing, park officials said. Reading or replaying the story in itsĪrchived form does not constitute a republication of the story. ![]() Only for your personal, non-commercial use. ![]() iPhone 15 Pro Max includes 256GB, 512GB, and 1TB.Īpple has been rumored to be going up to 2TB on the iPhone Pro line for a couple years now, but that’s still an iPad Pro and Mac-only option for now. iPhone 15 Pro storage includes 128GB, 256GB, 512GB, and 1TB. Apple Refurbished iPhone Refurbished iPhone 12 Pro Max 512GB - Graphite. The move does create a minor difference between the Pro and Pro Max line this year though: iPhone 15 Pro comes in four storage options, and iPhone 15 Pro Max only comes in three storage options. Refurbished iPhone 12 Pro Max 512GB - Graphite (Unlocked). The iPhone 12 Pro Max uses a partially 'surgical grade' stainless steel case with flat polished stainless steel sides and has a glass front and back. That’s the same price as the iPhone 14 Pro Max with 256GB storage.Ĭonsumers would obviously be more content with a $1099 iPhone 15 Pro Max option with 128GB, but at least we’re not dealing with paying $100 more for the same storage as last year. Apple notes that the iPhone 12 Pro Max provides 'computational photography' features that improve low-light performance and reduce noise compared to earlier iPhone models. The new entry level storage for iPhone 15 Pro Max is 256GB for $1199. Instead, Apple dropped the 128GB storage option from the iPhone 15 Pro Max line. iPhone 15 Pro Max starts at $1199, up from $1099 with the iPhone 14 Pro, although it’s not a straight $100 price increase. Apple iPhone 12 Pro Max 6GB 512GB Silver Network Technology, GSM / CDMA / HSPA / EVDO / LTE / 5G Display Type, Super Retina XDR OLED, HDR10, 800 nits (typ). The story is a little different for iPhone 15 Pro Max, which now carries the highest starting price of any iPhone yet. Not bad when you consider all that’s new with the new model. How did those rumors shake out? Fortunately, the iPhone 15 Pro has the same starting price of $999 for 128GB storage as the iPhone 14 Pro. Several analysts expected iPhone 15 Pro and 15 Pro Max to cost $100-$200 more without changing storage options. Productos similares: 480 Móviles Apple Smartphone 4G Phablet 225 Móviles 5G Apple. Apple has been rumored to be planning a price increase for its Pro models for years now. Móvil 5G 6,7 pulgadas Resolución de pantalla Full HD 48 megapíxeles Memoria RAM 6 GB 512 GB iOS 16 Capacidad de la batería 4.323 mAh Ficha del producto. ![]() But much as Eric embodies a stalwart, if fretful, morality, Hanssen remains a cipher, apparently untroubled by his lies and hypocrisies. Parallel investigations and multiple layers of deceit are galvanized by smart, taut, mostly understated performances. The film focuses on Eric and Hanssen's tight, tense association, as each suffers differently for the lies he's forced to tell. This successful production should please those with an appreciation for complex dramas with a basis in factual characters.īreach can't seem to get around the mystery that Hanssen presents. American-born Cinematographer Tak Fujimoto creates mystic images, while Composer Michael Danna matches his compositions and carries the moods. As always, the strength of the central performances will differ with each viewer’s attachment to those cast in respective roles but generally, all acquit themselves well, with Chris Cooper particularly eerie as Hanssen.ĭirector/co-screen adaptor Billy Ray thankfully avoids over-indulging in too much modern sensationalism - apart from the totally fictionalized, sexual perversions of the main character. That said, this production remains superior movie entertainment. While based on specific amazing facts regarding anti-American spy Robert Hanssen, many situations are fabrications of the screenwriter. Thanks to a friend’s recommendation I came late to this one and while constantly watchable (in fact quite engrossing) Breach is to be taken as a Hollywood product. ![]() What are some tips for making homemade cornbread as delicious as homemade? If you use two Jiffy Corn Muffin Mix boxes instead of one, the cornbread will be thicker and more authentic. This savory treat can be made in just 20 minutes with a box of Jiffy Cornbread Mix. Let’s explore how you can use heavy cream in Jiffy cornbread and why it will make your cornbread stand out from the rest.Ĭornbread is an American staple that has spread to more and more dinner tables over the years. Whether you’re using a box mix or homemade, adding heavy cream to your cornbread can take it to the next level. But did you know that you can make a delicious, fluffy cornbread with a secret ingredient? With the addition of heavy cream, you can make a cornbread that is full of flavor, texture, and a unique richness. Cornbread is a favorite for sides, snacks, and even a main course. If you like this recipe, be sure to check out our entire side dish recipe section! Whether you’re making sides for a Thanksgiving feast, playing Christmas music while you prep Christmas dinner, or just looking for an easy weeknight side dish, we’ve got lots of options.Baking a delicious and satisfying cornbread is an essential part of many meals.
![]() The Arduino IDE is based on a simplified version of the C programming language and provides a user-friendly interface for programming and controlling the board's inputs and outputs. Operating Systems (OS) & approaches to softwareĪrduino IDE and Raspberry Pi microcontrollers have different operating systems (OS) and approaches to software.Īrduino has a simplified software environment known as the Arduino Integrated Development Environment (IDE), which is used to write and upload code to the board. ![]() Raspberry Pi Zero, on the other hand, uses a more powerful system-on-a-chip (SoC) that provides more processing power and memory, and a greater number of I/O pins. Arduino Uno uses a microcontroller that is designed to be simple and easy to use, with a limited number of I/O pins. One of the key differences between Arduino and Raspberry Pi is the type of microcontroller used. Unlike Arduino Uno, Raspberry Pi has a more powerful processor, more memory, and a greater number of I/O pins, making it ideal for complex projects that require higher processing power and connectivity options. Raspberry Pi Zero, on the other hand, is a small and inexpensive single-board computer that runs a full operating system, such as Raspbian, which is based on Linux. It has a straightforward programming environment based on a simplified version of the C programming language, and a limited number of input/output (I/O) pins that make it well-suited for simple projects that require basic control over sensors and actuators. ![]() Both have their own strengths and weaknesses, and choosing between the two depends on the specific requirements of a project.Īrduino Uno is a microcontroller board that was designed to provide a simple and accessible platform for beginners to learn electronics and programming. Arduino Vs Raspberry Pi: Which Is the Best Board for YouĪrduino and Raspberry Pi are two of the most popular single-board computers used by electrical engineers for various projects. |
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